Yazar "0000-0002-7957-110X" için Fakülteler listeleme
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Activation of methane by Os+: Guided-ion-beam and theoretical studies
Armentrout P.B.; Parke, Laura; Hinton, Christopher; Citir, Murat (CHEMM, 2013)Activation of methane by the third-row transition-metal cation Os + is studied experimentally by examining the kinetic energy dependence of reactions of Os+ with CH4 and CD4 using guided-ion-beam tandem mass spectrometry. ... -
A dopant-free 2,7-dioctyl[1]benzothieno[3,2-b][1]benzothiophene (C8-BTBT)-based hole transporting layer for highly stable perovskite solar cells with efficiency over 22%
Kaya, Ismail Cihan; Ozdemir, Resul; Usta, Hakan; Sonmezoglu, Savas (ROYAL SOC CHEMISTRY, 2022)In this study, for the first time, n-i-p PSCs were fabricated using dopant-free 2,7-dioctyl[1]benzothieno[3,2-b][1]benzothiophene (C8-BTBT) as the solution-processed hole transporting layer (HTL). The power conversion ... -
Engineering functionalized low LUMO [1]benzothieno[3,2-b][1]benzothiophenes (BTBTs): unusual molecular and charge transport properties
Ozdemir, Resul; Ahn, Kyunghan; Deneme, Ibrahim; Zorlu, Yunus; Kim, Dojun; Kim, Myung-Gil; Usta, Hakan (ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND, 2020)Diacene-fused thienothiophenes (DAcTTs) have provided an excellent pi-framework for the development of high mobility p-type molecular semiconductors in the past decade. However, n-type DAcTTs are rare and their electron ... -
Guided ion-beam and theoretical studies of the reaction of Os+ (6D) with O2: Adiabatic and nonadiabatic behavior
Hinton, Christopher S.; Citir, Murat; Armentrout P.B. (ELSEVIER, 2013)The kinetic-energy dependence of the Os+ + O2 reaction is examined using guided ion-beam mass spectrometry. The cross section for OsO+ formation from ground state Os+ (6D) is unusual, exhibiting two endothermic features. ... -
High Electron Mobility in [1]Benzothieno[3,2-b][1]benzothiophene-Based Field-Effect Transistors: Toward n-Type BTBTs
Usta, Hakan; Kim, Dojeon; Ozdemir, Resul; Zorlu, Yunus; Kim, Sanghyo; Ruiz Delgado, M. Carmen; Harbuzaru, Alexandra; Kim, Seonhyoung; Demirel, Gokhan; Hong, Jongin; Ha, Young-Geun; Cho, Kilwon; Facchetti, Antonio; Kim, Myung-Gil (AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA, 2019)The first example of an n-type [1]benzothieno[3,2-b][1]benzothiophene (BTBT)-based semiconductor, D-(PhFCO)-BTBT, has been realized via a two-step transition metal-free process without using chromatographic purification. ... -
Highly Efficient Deep-Blue Electroluminescence Based on a Solution-Processable A-pi-D-pi-A Oligo(p-phenyleneethynylene) Small Molecule
Usta, Hakan; Alimli, Dilek; Ozdemir, Resul; Dabak, Salih; Zorlu, Yunus; Alkan, Fahri; Tekin, Emine; Can, Ayse (AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA, 2019)The development of solution-processable fluorescent small molecules with highly efficient deep-blue electroluminescence is of growing interest for organic light-emitting diode (OLED) applications. However, high-performance ... -
A hybridized local and charge transfer excited state for solution-processed non-doped green electroluminescence based on oligo(p-phenyleneethynylene)
Usta, Hakan; Alimli, Dilek; Ozdemir, Resul; Tekin, Emine; Alkan, Fahri; Kacar, Rifat; Altas, Ahu Galen; Dabak, Salih; Gurek, Ayse Gul; Mutlugun, Evren; Yazici, Ahmet Faruk; Can, Ayse (ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND, 2020)We herein report a new highly efficient green emissive hot-exciton molecule, 1,4-bis((4'-diphenylamino3-cyano-[1,1'-biphenyl]-4-yl)ethynyl)-2,5-bis(2-ethylhexyloxy)benzene (2EHO-TPA-CNPE) that consists of an extended ... -
Interplay between Charge Injection, Electron Transport, and Quantum Efficiency in Ambipolar Trilayer Organic Light-Emitting Transistors
Moschetto, Salvatore; Benvenuti, Emilia; Usta, Hakan; Özdemir, Resul; Facchetti, Antonio; Muccini, Michele; Prosa, Mario; Toffanin, Stefano (WILEY, 2022)The fascinating characteristic of organic light-emitting transistors (OLETs) of being electrical switches with an intrinsic light-emitting capability makes them attractive candidates for a wide variety of applications, ... -
Meso-pi-Extended/Deficient BODIPYs and Low-Band-Gap Donor-Acceptor Copolymers for Organic Optoelectronics
Can, Ayse; Choi, Gi-Seok; Ozdemir, Resul; Park, Soyoon; Park, Jin Su; Lee, Yongchul; Deneme, Ibrahim; Mutlugun, Evren; Kim, Choongik; Kim, Bumjoon J.; Usta, Hakan (AMER CHEMICAL SOC, 2022)The realization of π-deficient acceptors and their donor− acceptor copolymers has become a key research focus for the realization of versatile organic optoelectronic materials and devices. Herein, we demonstrate the ... -
A Solution-Processable meso-Phenyl-BODIPY-Based n-Channel Semiconductor with Enhanced Fluorescence Emission
Ozcan, Emrah; Ozdemir, Mehmet; Ho, Dongil; Zorlu, Yunus; Ozdemir, Resul; Kim, Choongik; Usta, Hakan; Cosut, Bunyemin (WILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY, 2019)The cover feature shows the delicate balance between locally excited (LE) and twisted intramolecular charge-transfer (TICT) states, which could be controlled by solvent polarity and nano-aggregation, of a meso-phenyl-BODIPY-based ... -
Thermochemistry of alkali metal cation interactions with histidine: Influence of the side chain
Armentrout, P. B.; Citir, Murat; Chen, Yu; Rodgers, M. T. (American Chemical Society, 2012)The interactions of alkali metal cations (M+ = Na+ , K+ , Rb+ , Cs+ ) with the amino acid histidine (His) are examined in detail. Experimentally, bond energies are determined using threshold collision-induced ... -
Trans-cis isomerization assisted synthesis of solution-processable yellow fluorescent maleic anhydrides for white-light generation
Ozdemir, Mehmet; Genc, Sinan; Ozdemir, Resul; Altintas, Yemliha; Citir, Murat; Sen, Unal; Mutlugun, Evren; Usta, Hakan (ELSEVIER, 2015)Heterocyclic maleic anhydride derivatives have been extensively studied in natural products chemistry over the past few decades. However, their incorporation into optoelectronic devices has lagged behind that of other ...