Symmetric naphthalenediimidequaterthiophenes for electropolymerized electrochromic thin films
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info:eu-repo/semantics/closedAccessTarih
2015Yazar
Figa, V.Chiappara, C.
Ferrante, Francesco
Casaletto, Maria Pia
Principato, F.
Cataldo, Sebastiano
Chen, Z.
Usta, Hakan
Facchetti, A.
Pignataro, B.
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A new symmetric naphthalenediimidequaterthiophene (s-NDI2ODT4) was synthesized and exhibited the capability to electropolymerize alone or with EDOT affording polymers with controlled donor/acceptor monomer ratios. s-NDI2ODT4-EDOT-based copolymers showed low band gaps, wide optical absorption ranges extending to the near IR region, tuned electrical properties, thin-film surface morphology and hydrophilicity as well as high coloration efficiency in electrochromic devices.