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Anhydrous proton conducting poly(vinyl alcohol) (PVA)/ poly(2-acrylamido-2-methylpropane sulfonic acid) (PAMPS)/1,2,4-triazole composite membrane
Erkartal, Mustafa; Aslan, Ayse; Erkilic, Ufuk; Dadi, Seyma; Yazaydin, Ozgur; Usta, Hakan; Sen, Unal (Elsevier Ltd, 2016)The design and fabrication of anhydrous proton exchange membranes are critically important for high temperature proton exchange membrane fuel cell (HT-PEMFC) operating between 100 and 200 °C. Herein, we demonstrate a novel ... -
Boronic Acid Moiety as Functional Defect in UiO-66 and Its Effect on Hydrogen Uptake Capacity and Selective CO2 Adsorption: A Comparative Study
Erkartal, Mustafa; Sen, Unal (AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA, 2018)Herein, we use linker fragmentation approach to introduce boronic acid moieties as functional defects into Zr-based metal organic frameworks (MOFs, UiO-66). Our findings show that the amount of permanently incorporated ... -
Development of highly transparent Pd-coated Ag nanowire electrode for display and catalysis applications
Canlier, Ali; Ucak, Umit Volkan; Usta, Hakan; Cho, Changsoon; Lee, Jung-Yong; Sen, Unal; Citir, Murat (ELSEVIER, 2015)Ag nanowire transparent electrode has excellent transmittance (90%) and sheet resistance (20 Omega/sq), yet there are slight drawbacks such as optical haze and chemical instability against aerial oxidation. Chemical stability ... -
Enhancement of Anhydrous Proton Conductivity of Poly(vinylphosphonic acid)-Poly(2,5-benzimidazole) Membranes via In Situ Polymerization
Sen, Unal; Usta, Hakan; Acar, Oktay; Citir, Murat; Canlier, Ali; Bozkurt, Ayhan; Ata, Ali (WILEY-V C H VERLAG GMBH, 2015)Polymer electrolyte membranes (PEMs) are synthesized via in situ polymerization of vinylphosphonic acid (VPA) within a poly(2,5-benzimidazole) (ABPBI) matrix. The characterization of the membranes is carried out by using ... -
Micro-/Nanostructured Highly Crystalline Organic Semiconductor Films for Surface-Enhanced Raman Spectroscopy Applications
Yilmaz, Mehmet; Ozdemir, Mehmet; Erdogan, Hakan; Tamer, Ugur; Sen, Unal; Facchetti, Antonio; Usta, Hakan; Demirel, Gokhan (WILEY-V C H VERLAG GMBH, 2015)The utilization of inorganic semiconductors for surface-enhanced Raman spectroscopy (SERS) has attracted enormous interest. However, despite the technological relevance of organic semiconductors for enabling inexpensive, ... -
Proton conducting poly(vinyl alcohol) (PVA)/poly (2-acrylamido-2-methylpropane sulfonic acid) (PAMPS)/zeolitic imidazolate framework (ZIF) ternary composite membrane
Erkartal, Mustafa; Usta, Hakan; Citir, Murat; Sen, Unal (ELSEVIERRADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS, 2016)The design, synthesis and characterization of novel proton exchange membranes (PEMs) are of significant scientific and technological importance for the realization of fuel cells, actuators, and sensors. Here, we demonstrate ... -
Proton Conducting Self-Assembled Metal-Organic Framework/Polyelectrolyte Hollow Hybrid Nanostructures
Sen, Unal; Erkartal, Mustafa; Kung, Chung-Wei; Ramani, Vijay; Hupp, Joseph T; Farha, Omar K. (AMER CHEMICAL SOC1155 16TH ST, NW, WASHINGTON, DC 20036, 2016)Herein, a room temperature chemical process to synthesize functional, hollow nanostructures from zeolitic imidazolate framework-8 (ZIF-8) and poly(vinylphosphonic acid) (PVPA) is reported. Syntheses are initiated by ... -
Proton-conducting blend membranes of Nafion/poly(vinylphosphonic acid) for proton exchange membrane fuel cells
Acar, Oktay; Celik, Sevim Unugur; Bozkurt, Ayhan; Ata, Ali; Tokumasu, Takashi; Miyamoto, Akira; Sen, Unal (SPRINGER, 2013)Nafion/poly(vinylphosphonic acid) blends were synthesized and characterized in this work. Poly(vinylphosphonic acid), PVPA, was synthesized by the free-radical polymerization of vinylphosphonic acid. Then Nafion/PVPA ... -
Thin films of inert metal nanowires for display applications
Citir, Murat; Sen, Unal; Usta, Hakan; Canlier, Ali (TANGER LTD, 2015)Ag nanowire transparent electrode has excellent transmittance (90%) and sheet resistance (20 Ohm/sq), yet there are slight drawbacks such as optical haze and chemical instability against aerial oxidation. Chemical stability ... -
Trans-cis isomerization assisted synthesis of solution-processable yellow fluorescent maleic anhydrides for white-light generation
Ozdemir, Mehmet; Genc, Sinan; Ozdemir, Resul; Altintas, Yemliha; Citir, Murat; Sen, Unal; Mutlugun, Evren; Usta, Hakan (ELSEVIER, 2015)Heterocyclic maleic anhydride derivatives have been extensively studied in natural products chemistry over the past few decades. However, their incorporation into optoelectronic devices has lagged behind that of other ...